Liquid-phase exfoliation (LPE) has been introduced as a versatile and scalable production method for two-dimensional (2D) materials. This method yields dispersions that allow for the fabrication of printable and flexible electronic devices. However, the fabrication of uniform and homogeneous films from LPE dispersions with a performance similar to that of bottom-up grown materials remains a challenge, as the film quality strongly influences the optical and electrical performance of devices. Furthermore, longterm stability remains a major challenge for all 2D material based applications. In this study, we report on highly conductive tiled network films made of platinum diselenide (PtSe₂) flakes derived using a scalable LPE method. We characterized the homogeneous films in terms of morphology and electrical behavior. As an example of applicability, we produce a chemiresistive sensor structure with the PtSe₂ films and show significant resistance changes upon periodic ammonia gas exposures, revealing a sub- 0.1 part per million (ppm) detection limit (DL). More remarkably the devices are fully functional after 15 months, underlining the high stability of PtSe₂ based devices.